Atmospheric sciences colloquia

Atmospheric sciences colloquia

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Event Detail Information

Event Detail Information

New Measurements of Clusters and Nanoparticles: Implications for Atmospheric Nucleation & Growth Models


Professor Peter McMurry, Department of Mechanical Engineering, University of Minnesota

Date Jan 30, 2013
Time 3:00 pm  

Room 112 of the Transportation Building


Department of Atmospheric Sciences


Shirley Palmisano

Phone 217-244-5737
Event type Graduate colloquium
Views 694

The formation of new particles from “extremely minute quantities of matter” (John Aitken, 1911) contributes significantly to the global concentrations of atmospheric particles and cloud condensation nuclei (CCN). Through their role as CCN, these particles affect the earth’s radiation budget, so it is important to account for them in climate models. Challenges in this work involve identifying the trace species that participate in nucleation and growth, measuring their concentrations (typical mole fractions are 10-14 to 10-11), and understanding the chemical mechanisms by which particles are formed from gases and subsequently grow. This presentation will describe our progress at developing suitable measurement methods and using this new information to gain insights about the chemical and physical processes that determine nucleation and growth rates. Measurements of the complete particle number distributions during nucleation events, including molecules and neutral molecular clusters, will be described. Evidence will be shown that the smallest stable particles contain just a few (two to four) sulfuric acid molecules, and that uptake of sulfuric acid vapor for particles larger than this is collision-limited.


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