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Condensed Matter Seminar: Screening of charge and structural motifs in oxides

Event Type
Seminar/Symposium
Sponsor
Physics
Location
190 Engineering Sciences Bldg - corner Goodwin & Springfield 
Date
Mar 8, 2013   1:00 pm  
Speaker
Peter B. Littlewood - Assoc. Director - Physical Sciences and Engineering - Argonne National Laboratory Prof of Physics - James Franck Institute - University of Chicago
Contact
Peggy Pennell
E-Mail
ppennell@illinois.edu
Phone
217/244-7636
Views
1421
Originating Calendar
Physics - Condensed Matter Seminar

Heterostructure oxides offer the opportunity to build in electric fields by precise control of chemistry on the atomic scale, used recently to generate modulation doping of two- dimensional electron gases (2DEG) in oxides. The origin of the 2DEG, whether in pristine or defected materials, is under debate. I will discuss the role of surface redox reactions, in particular O vacancies, as the source of mobile carriers, and also discuss their role in the switching of ferroelectricity in ultra-thin films.

While electric charges can be screened by mobile carriers, the same is not true of strain fields, which have intrinsic long-range interactions that cannot be screened. When strain fields are produced as a secondary order parameter in phase transitions - as for example in ferroelectrics - this produces unexpected consequences for the dynamics of order parameter fluctuations, including the generation of a gap in what would otherwise have been expected to be Goldstone modes. In some cases, eg manganites and nickelates, other intra-cell modes can nonlinearly screen the order parameter, which produces a strong sensitivity of ordering to octahedral rotations, essentially a jamming transition.

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