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Event Detail Information

Condensed Matter Seminar: Screening of charge and structural motifs in oxides

Speaker

Peter B. Littlewood -
Assoc. Director - Physical Sciences and Engineering - Argonne National Laboratory
Prof of Physics - James Franck Institute - University of Chicago

Date Mar 8, 2013
Time 1:00 pm  
Location

190 Engineering Sciences Bldg - corner Goodwin & Springfield

 

Sponsor Physics
Contact Peggy Pennell
Phone 217/244-7636
Event type CM Seminar
Views 1421
Originating Calendar Physics - Condensed Matter Seminar

Heterostructure oxides offer the opportunity to build in electric fields by precise control of chemistry on the atomic scale, used recently to generate modulation doping of two- dimensional electron gases (2DEG) in oxides. The origin of the 2DEG, whether in pristine or defected materials, is under debate. I will discuss the role of surface redox reactions, in particular O vacancies, as the source of mobile carriers, and also discuss their role in the switching of ferroelectricity in ultra-thin films.

While electric charges can be screened by mobile carriers, the same is not true of strain fields, which have intrinsic long-range interactions that cannot be screened. When strain fields are produced as a secondary order parameter in phase transitions - as for example in ferroelectrics - this produces unexpected consequences for the dynamics of order parameter fluctuations, including the generation of a gap in what would otherwise have been expected to be Goldstone modes. In some cases, eg manganites and nickelates, other intra-cell modes can nonlinearly screen the order parameter, which produces a strong sensitivity of ordering to octahedral rotations, essentially a jamming transition.